I found some really useful guides on the RR forum, plus I have a Haynes manual which had clear instructions, so I followed those pretty closely (and did it with a friend in case I came unstuck!).
Having now done it, I'd say it's a pretty straightforward one man job. Obviously you'll need a decent chain breaker/rivet tool (don't get a cheap one... ;)) and the usual sockets and torque wrenches. I found the most challenging was getting my rear wheel back on, which I did unaided. The spacers kept falling out and typically I was working on a surface covered in small stones and grit, so had to regrease them every time.
Eventually I managed to line everything up and lift the wheel back into place slotting the disc back in between the caliper/pads. Then it was simply a case of realigning the wheel, adjusting the chain tension and it was done.
I think you're pretty handy with the spanners so I can't imagine you'll have any issues. What kit have you gone with?